The Curies were among the finest scientists the world had known, and their dedication to task, observational ability, and logic were second to none, but their carelessness with radioactive substances was practically suicidal. Marie loved to carry a vial of a radium salt in a pocket of her lab smock, because it glowed such a pretty blue color, and she could take it out and show visitors. Pierre enjoyed lighting up a party at night using glass tubes, coated inside with zinc sulfide and filled with a radium solution, showing off their discovery to amazed guests. He got it all over his hands, and on swollen digits the skin peeled off. Surely, the cause and effect were obvious.[7]
In 1904 Thomas A. Edison, the “Wizard of Menlo Park,” had been experimenting with x-rays for several years. Edison thought of using x-rays to make a fluorescent lamp, and he proceeded to test a multitude of materials to find which one would glow the brightest under x-rays. His faithful assistant was a young, eager fellow, Charles M. Dally, who had worked for him for the past 14 years.
Dally was born in Woodbridge, New Jersey, in 1865, and he had served in the United States Navy for six years as a gunner’s mate. After discharge from the Navy he signed on at the Edison Lamp Works in Harrison, New Jersey, as a glass blower, and in 1890 he moved to the Edison Laboratory in West Orange to work directly for Mr. Edison. He was put to work evaluating the new lamp technology. Day after day, he held up screens of fluorescent material in front of an operating x-ray tube, staring directly at it to determine the quality of the light it produced. Nobody gave thought to any danger, but after a while Edison noticed that he could no longer focus his eye that he used briefly to test a new fluoroscope, and “the x-ray had affected poisonously my assistant, Mr. Dally.”
In the beginning Dally’s hair began to fall out and his face began to wrinkle. His eyelashes and eyebrows disappeared, and he developed a lesion on the back of his left hand. Dally usually held the fluorescent screen in his right hand in front of the x-ray tube, and tested it by waving his left hand in the beam. There was no acute pain, only a soreness and numbness. Dally kept testing the fluorescent screens. His solution to the physical deterioration was to swap hands, using his right to wave in front of the beam.
The lesion on his left hand would not heal, and conventional medical practice was at a loss to explain why. The pain became intolerable, and attempts to graft new skin onto the spreading sore were unsuccessful. The vascular system in the hand collapsed, and a cancer was detected at the base of the little finger. The physicians had no choice but to amputate the left hand at the wrist. Dally kept working on the x-ray project, holding the apparatus with his right and waving the stump in front of the screen.
In the meantime a deep ulceration developed on his right hand, and four fingers had to be removed. Eventually, both arms had to be amputated, one at the shoulder and the other above the elbow. All efforts to stop the progression of the disease eventually failed and Dally, after eight years of suffering, died in October of 1904. Edison was shaken, and he dropped all work on the fluorescent lamp. “I am afraid of radium and polonium too,” he commented, “and I don’t want to monkey with them.”
At the time there were no rules, regulations, laws, procedures, or helpful suggestions for the handling and storage of radioactive materials. It was understood that radioactivity could be induced artificially with electrical equipment, or it could be found in nature. The new elements that the Curies had extracted at great labor from uranium ore, radium and polonium, would turn out to be two of the most dangerous substances in the natural world, and both are banned from all but the most critical industrial uses. Both are alpha-ray emitters. An alpha ray is a particle, consisting of a clump of two protons and two neutrons. It is literally the nucleus of a helium atom, and it breaks free of the radium nucleus, flying outward into space.
In 1903 the physicist Ernest Rutherford calculated that the energy released from radium by a single alpha particle is a million times larger than the energy produced by any chemical combination of two molecules. The alpha particle has very limited range, and it is easily stopped by the uppermost layer of the skin, but the damage to healthy tissue to this shallow depth is significant. The greatest danger is in ingesting or breathing radium dust, as the destructive energy of each alpha particle released is fully deposited in body tissues. Atop that danger, there is the continuing breakdown of the decay products, the debris left after an alpha particle has jumped off the radium or polonium nucleus. These damaged nuclei emit an entire range of different radiations from further decays. By the time of Rutherford’s calculation, Pierre Curie was suffering unbearable pain from burns all over his body. He would lie in bed all night, unable to sleep, moaning. As a professor at the Sorbonne, the distinguished University of Paris, he asked for a reduced teaching load, complaining of having only “a very feeble capacity for work” due to his work refining radium out of uranium ore.
On April 19, 1906, after a luncheon of the Association of Professors of the Science Faculties, he walked to his publisher’s office to go over some proofs of his latest scientific paper. It was raining hard, and the street traffic was heavy. He found his publisher locked and closed down, due to a strike. Curie then turned and stepped into the rue Dauphine to cross, slipped on a wet cobblestone, and sprawled into the street. His head went under the wheel of a 6-ton, horse-drawn wagon loaded down with military uniforms. Curie died instantly.
It took 11 years, but eventually news of the discovery of radium penetrated the Ozark Territory, and in 1909 James L. Leib, a prospector and self-schooled geologist, saw a logical connection between the published properties of radium and the legend of the mysterious cave dating back to 1879. The spot price of radium at the time was, gram for gram, about one hundred times the value of diamonds, or $70,000 per gram. It was the most valuable material in the world, as it had found use in cancer therapy. It was true that radium would kill living tissue, but its working range was very slight. A carefully placed radium needle would wipe out a cancer tumor immediately adjacent to it without harming anything else. There was much demand.
With effort, Leib found the remaining member of the hunting party, Old Bill Boyceyer, still alive in Chance, Oklahoma. Old Bill was glad to tell the story yet again and give what he could remember as directions to the hole, with a caution: Don’t go in!
Leib found the cave, right where Boyceyer remembered, and he entered with unusual caution. He went in only far enough to pick up some bits of weird-looking, bluish rocks. Leib corresponded directly with Madame Curie, obtaining instructions for exposing photographic plates to the ore and confirming radioactivity. With the help of a photographer in Bentonville, Missouri, he succeeded. The few rocks he had brought back from the hole burned dark images into the plates, right through the dark-slides and black paper wrapping. Steel nails and a key left atop the plates showed up clearly as shadows, blocking the radiation. The radiographs were displayed at county fairs and apple shows all over the Ozarks, with Leib trying to drum up interest in opening up a radium mine. There were fortunes to be made, far greater than could be extracted from a mere gold mine.
7
Or were they? Much has been repeated about Pierre Curie’s radiation burns on his hands and fingers and later on his body. Consider, instead, the fact that for every ton of uranium ore the Curies processed in their crude laboratory, they had to use five tons of concentrated sulfuric and hydrochloric acid. Over a few years, they ran through eight tons of ore. Although the Curies were brilliant, creative scientists, their laboratory hygiene was not really up to the standards of the time, and Pierre was the less careful of the two. He didn’t even wear gloves, and he got acid all over himself. Sulfuric acid desiccates living tissue, killing it, and hydrochloric acid digests it.