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Watercolours are pigments ground with gum arabic and gall and thinned with water in use. Sable and squirrel (“camel”) hair brushes are used on white or tinted paper and card.

Dürer, Albrecht: The Monumental TurfThe Monumental Turf, watercolour painting by Albrecht Dürer, 1503; in the Albertina, Vienna. 41 × 31.5 cm.Courtesy of the Albertina, Vienna

Three hundred years before the late 18th-century English watercolourists, German artist Albrecht Dürer anticipated their technique of transparent colour washes in a remarkable series of plant studies and panoramic landscapes. Until the emergence of the English school, however, watercolour became a medium merely for colour tinting outlined drawings or, combined with opaque body colour to produce effects similar to gouache or tempera, was used in preparatory studies for oil paintings.

The chief exponents of the English method were Thomas Girtin, John Sell Cotman, John Robert Cozens, Richard Parkes Bonington, David Cox, and Constable. Turner, however, true to his unorthodox genius, added white to his watercolour and used rags, sponges, and knives to obtain unique effects of light and texture. Victorian watercolourists, such as Birket Foster, used a laborious method of colour washing a monochrome underpainting, similar in principle to the tempera-oil technique. Following the direct, vigorous watercolours of the French Impressionists and Post-Impressionists, however, the medium was established in Europe and America as an expressive picture medium in its own right. Notable 20th-century watercolourists were Wassily Kandinsky, Paul Klee, Raoul Dufy, and Georges Rouault; the U.S. artists Winslow Homer, Thomas Eakins, Maurice Prendergast, Charles Burchfield, John Marin, Lyonel Feininger, and Jim Dine; and the English painters John and Paul Nash.

Turner, J.M.W.: The Lauerzersee with Schwyz and the MythenThe Lauerzersee with Schwyz and the Mythen, pencil, pen, ink, and watercolour on paper by J.M.W. Turner, c. 1848.In a private collection

In the “pure” watercolour technique, often referred to as the English method, no white or other opaque pigment is applied, colour intensity and tonal depth being built up by successive, transparent washes on damp paper. Patches of white paper are left unpainted to represent white objects and to create effects of reflected light. These flecks of bare paper produce the sparkle characteristic of pure watercolour. Tonal gradations and soft, atmospheric qualities are rendered by staining the paper when it is very wet with varying proportions of pigment. Sharp accents, lines, and coarse textures are introduced when the paper has dried. The paper should be of the type sold as “handmade from rags”; this is generally thick and grained. Cockling is avoided when the surface dries out if the dampened paper has been first stretched across a special frame or held in position during painting by an edging of tape. Ink

Ink is the traditional painting medium of China and Japan, where it has been used with long-haired brushes of wolf, goat, or badger on silk or absorbent paper. Asian black ink is a gum-bound carbon stick that is ground on rough stone and mixed with varying amounts of water to create a wide range of modulated tones or applied almost dry, with lightly brushed strokes, to produce coarser textures. The calligraphic brush technique is expressive of Zen Buddhist and Confucian philosophies, brush-stroke formulas for the spiritual interpretation of nature in painting dictating the use of the lifted brush tip for the “bone,” or “lean,” structure of things and the spreading belly of the hairs for their “flesh,” or “fat,” volumes. The East Asian artist poises the brush vertically above the paper and controls its rhythmic movements from the shoulder. Distant forms represented in landscapes painted on silk were sometimes brushed on from the reverse side.

Hokusai: Detail of Woodcutter Gazing at WaterfallWoodcutter Gazing at Waterfall (detail) by Hokusai, ink and colour on paper scroll, 1798; in the Iris & B. Gerald Cantor Center for Visual Arts, Stanford, California.Courtesy of the Stanford University Museum of Art, California, Ikeda Collection

In the Western world, ink has been used rather more for preparatory studies and topographical and literary illustrations than as a medium for easel paintings. Western artists have generally combined ink washes with contours and textures in quill or steel pen. Among the finest of these are by Rembrandt, Nicolas Poussin, Francisco Goya, Samuel Palmer, Constable, and Édouard Manet. Claude Lorrain, Turner, and Daumier and, in the 20th century, Braque, Picasso, Reginald Marsh, Henri Michaux, and John Piper are some of those who have exploited its unique qualities. Modern artists also use ballpoint and felt pens. Gouache

Gouache is opaque watercolour, known also as poster paint and designer’s colour. It is thinned with water for applying, with sable- and hog-hair brushes, to white or tinted paper and card and, occasionally, to silk. Honey, starch, or acrylic is sometimes added to retard its quick-drying property. Liquid glue is preferred as a thinner by painters wishing to retain the tonality of colours (which otherwise dry slightly lighter in key) and to prevent thick paint from flaking. Gouache paints have the advantages that they dry out almost immediately to a matte finish and, if required, without visible brush marks. These qualities, with the capacities to be washed thinly or applied in thick impasto and a wide colour range that now includes fluorescent and metallic pigments, make the medium particularly suited to preparatory studies for oil and acrylic paintings. It is the medium that produces the suede finish and crisp lines characteristic of many Indian and Islamic miniatures, and it has been used in Western screen and fan decoration and by modern artists such as Rouault, Klee, Jean Dubuffet, and Morris Graves.

Daumier, Honoré: At the Palais de JusticeAt the Palais de Justice, gouache on paper by Honoré Daumier; in the Musée du Petit Palais, Paris.Giraudon/Art Resource, New York Encaustic

Encaustic painting (from the Greek: “burnt in”) was the ancient method, recorded by Pliny, of fixing pigments with heated wax. It was probably first practiced in Egypt about 3000 bce and is thought to have reached its peak in Classical Greece, although no examples from that period survive. Pigments, mixed with melted beeswax, were brushed onto stone or plaster, smoothed with a metal spatula, and then blended and driven into the wall with a heated iron. The surface was later polished with a cloth. Leonardo and others attempted unsuccessfully to revive the technique. American Indians" class="md-crosslink">North American Indians used an encaustic method whereby pigments mixed with hot animal fat were pressed into a design engraved on smoothed buffalo hide.

Mummy portrait of a young girl, encaustic painting from Al-Fayyūm, Egypt, 2nd century; in the Louvre, Paris.Giraudon/Art Resource, New York

A simplified encaustic technique uses a spatula to apply wax mixed with solvent and pigment to wood or canvas, producing a ridged, impasto surface. This is an ancient and most durable medium. Coptic mummy portraits from the 1st and 2nd centuries ce retain the softly blended, translucent colouring typical of waxwork effigies. In the 19th century Vincent van Gogh also used this method to give body to his oil pigment; the Neo-Impressionist artist Louis Hayet applied encaustic to paper, and it was used by U.S. painter Jasper Johns for his iconic paintings of maps, targets, and flags. Coloured wax crayons have also been used by modern painters such as Picasso, Klee, Arshile Gorky, and Hockney. Casein