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Although Peter allowed the election of a successor to Mazepa, the Hetmanate’s autonomous prerogatives were severely curtailed and underwent further weakening over the remaining decades of the 18th century. From 1722 to 1727 and again from 1734 to 1750, the office of hetman was in abeyance, as the Russian imperial regime introduced new institutions to oversee the country’s governance. In 1750 Empress Elizabeth revived the hetmancy for Kyrylo Rozumovsky, the brother of her favourite. On the accession of Catherine II (the Great) in 1762, the hetman and the starshyna petitioned for the restoration of the Hetmanate’s previous status; instead, in 1764 Catherine forced Rozumovsky’s resignation. Over the next 20 years all vestiges of Ukrainian autonomy were eliminated, and in 1775 the Zaporozhian Sich, the bastion of the Cossacks, was destroyed by Russian troops.

To the east of the Hetmanate lay lands that until the 17th century had remained largely unpopulated—part of the “wild fields” since the Mongol invasion. Into this area, starting in the late 16th century, the Muscovite government gradually extended its line of fortifications against the Tatars. In the 17th century this territory became an area of colonization by Ukrainian peasants and Cossacks fleeing Polish rule and, later, the ravages of the Ruin period. The newcomers established free, nonserf settlements called slobodas that gave the area the name of Sloboda Ukraine. Kharkiv developed into the region’s main centre. Like the Hetmanate, Sloboda Ukraine enjoyed extensive internal autonomy, though under officials appointed by the Russian imperial government. The autonomy of Sloboda Ukraine was abolished under Catherine in 1765.

Right Bank and western Ukraine until the Partitions of Poland

The western Ukrainian lands of Galicia and Volhynia, though part of the theatre of war during the Khmelnytsky insurrection, remained in its aftermath still firmly under Polish control. The Right Bank, after the abatement of the Ruin and the retrocession of Podolia by the Turks, also reverted to Polish sovereignty. However, only in 1714, after further dislocations connected with the Second Northern War, was control reestablished over the area by a greatly weakened Poland.

The society that reemerged in Ukrainian territories under Polish rule in the 18th century differed markedly from that in the Hetmanate. The Cossacks virtually disappeared as a significant organized force. Cities and towns experienced a serious decline, and their populations became more heavily Polish and, especially in the Right Bank, Jewish. Roman Catholicism maintained and even enhanced its earlier privileged status; the Uniate church, however, became predominant among Ukrainians, with Orthodoxy claiming a smaller number of adherents.

In the absence of strong central authority and with the elimination of the Cossacks as a countervailing force, the Right Bank was dominated by the Polish nobility. Especially influential were a few magnate families whose huge estates formed virtually independent fiefdoms, with their own privately armed militias. The desolated lands were slowly repopulated through peasant migrations (frequently organized by the nobility) from Galicia and, especially, Volhynia. The extreme exploitation of the enserfed peasantry bred discontent that led sporadically to uprisings by bands of rebels called haydamaks (Turkish: “freebooters” or “marauders”). The most violent, known as the Koliivshchyna, occurred in 1768 and was put down only with the help of Russian troops.

Polish rule in Ukrainian territories came to an end with the extinction of the Polish-Lithuanian Commonwealth in three partitions—in 1772, 1793, and 1795 (see Partitions of Poland). In the first partition, Galicia was annexed by Habsburg Austria. In the second, Russia took the Right Bank and eastern Volhynia; it absorbed the rest of Volhynia in the third.

Ukraine under direct imperial Russian rule

Following the abolition of autonomy in the Hetmanate and Sloboda Ukraine and the annexation of the Right Bank and Volhynia, Ukrainian lands in the Russian Empire formally lost all traces of their national distinctiveness. The territories were reorganized into regular Russian provinces (guberniyas) administered by governors appointed from St. Petersburg. The Right Bank, along with some adjoining territories, formed part of the Pale of Settlement, to which the Jewish population of the empire was residentially restricted (see pale). With the liquidation of the Sich and the annexation of the Crimean khanate in 1783, the sparsely settled southern lands (named Novorossiya, or New Russia) were colonized by migrants from other parts of Ukraine, as well as smaller numbers from Russia, the Balkans, and Germany. This colonization movement greatly expanded Ukrainian ethnic territory. The new Black Sea port of Odessa (Odesa) grew into a large and cosmopolitan metropolis.

Equally important developments occurred in the social sphere. As compensation for their lost rights as a ruling elite in the Hetmanate, the Cossack starshyna were equalized with the Russian nobility; many entered imperial service, and some achieved the highest government ranks. Through education, intermarriage, and government service, the Ukrainian nobility gradually became Russified—as the earlier Ruthenian nobility had been Polonized—though many retained a sentimental attachment to the land and its folklore. The Polish nobility in the Right Bank continued as the dominant landowning class, although its status eroded over time, particularly after the Polish insurrections of 1830–31 and 1863–64 (see November Insurrection; January Insurrection). The large Jewish population was bound by numerous legal disabilities and, from 1881, victimized by recurrent waves of pogroms. The gradual process of enserfment of the peasantry in the Left Bank culminated in 1783 under Catherine II. The obligations there, however, were less onerous than in the Right Bank. Agitation among the peasant class, coupled with the Russian defeat in the Crimean War (1853–56), hastened the decline of serfdom, but it remained the dominant lot of the peasantry until the emancipation of 1861. After emancipation, the peasants were still burdened by inadequate land allotments and heavy redemption payments that led to the impoverishment of many.

Nevertheless, the reforms stimulated the development of industry within the Russian Empire by releasing labour from the land. Industrial development was especially marked in eastern Ukraine, notably the Donbas region (Donets Basin). However, the workers attracted to the growing metallurgical industry and other industrial concerns generally came from other parts of the empire; the Ukrainian population seeking economic improvement more commonly emigrated to agricultural lands. As a result, the emerging working class and the growing urban centres in Ukraine became highly Russified islands in a Ukrainian rural sea.

As in the political and social realms, in religious policy the tsarist regime promoted the elimination of Ukrainian peculiarities. Although the largely Polish Roman Catholic Church was allowed to continue, Catherine launched a program of administrative conversion of Ukrainians from the Uniate church. The anti-Uniate campaign was partially reversed by her immediate successors but was renewed with vigour by Nicholas I. In 1839 the Uniate metropolitanate was abolished, the Union of Brest-Litovsk declared null and void, and the Uniates finally absorbed into the Russian Orthodox Church, while the recalcitrant clergy were harshly punished. The Russian Orthodox Church became an important vehicle for the Russification policies of the imperial regime in Ukraine.